4.7 Article

Aerobic alcohol oxidation by ruthenium species stabilized on nanocrystalline magnesium oxide by basic ionic liquids

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 9, Pages 1225-1229

Publisher

WILEY-BLACKWELL
DOI: 10.1002/adsc.200800013

Keywords

aerobic oxidation; alcohols; choline hydroxide; heterogeneous catalysis; nanocrystalline MgO; ruthenium

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The selective oxidation of various alcohols into their corresponding aldehydes and ketones was achieved by ruthenium species stabilized on the nanocrystalline magnesium oxide (NAP-MgO) by the incorporation of choline hydroxide, a basic ionic liquid, in excellent yields. The procedure is simple, efficient and environmentally benign. The catalyst can be used for four cycles with almost consistent activity.

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