Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 350, Issue 6, Pages 822-827Publisher
WILEY-BLACKWELL
DOI: 10.1002/adsc.200800018
Keywords
amines; molecular hydrogen; nanocrystalline magnesium oxide; nitro group; palladium(0); reduction
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An efficient, mild and selective synthesis of aromatic and aliphatic amines from the corresponding nitro compounds has been realized by using a ligand-free heterogeneous nanocrystalline magnesium oxide-stabilized palladium(0) catalyst, employing molecular hydrogen as the reductant. The catalyst is recovered quantitatively by simple filtration and was reused for several cycles with consistent activity.
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