Journal
ADVANCED MATERIALS
Volume 27, Issue 7, Pages 1223-1228Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201403475
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Funding
- DFG [SPP-1355]
- Emmy Noether Program
- EU
- BMBF [FKZ 03IS2151D]
- European Community [C25 Rhin-Solar]
- U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886]
- U.S. Department of Energy, Division of Basic Energy Sciences [DE-FG02-10ER4779]
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PCPDTBT, a marginally crystallizable polymer, is crystallized into a new crystal structure using solvent-vapor annealing. Highly ordered areas with three different polymer-chain orientations are identified using TEM/ED, GIWAXS, and polarized Raman spectroscopy. The optical and structural properties differ significantly from films prepared by standard device preparation protocols. Bilayer solar cells, however, show similar performance.
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