4.8 Article

Heat- or Water-Driven Malleability in a Highly Recyclable Covalent Network Polymer

Journal

ADVANCED MATERIALS
Volume 26, Issue 23, Pages 3938-3942

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201400317

Keywords

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Funding

  1. National Science Foundation [DMR-1055705, CMMI-1404627]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Materials Research [1055705] Funding Source: National Science Foundation

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A catalyst-free malleable network polymer that can be reprocessed by application of either water or heat is prepared through imine chemistry. This material is recycled from a fine powder to a coherent solid with >100% recycling efficiency through several generations. It is also reprocessed at ambient temperature using only water, thus potentially leading to energy-neutral green processing of the material.

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