4.8 Article

A Honeycomb-Layered Na3Ni2SbO6: A High-Rate and Cycle-Stable Cathode for Sodium-Ion Batteries

Journal

ADVANCED MATERIALS
Volume 26, Issue 36, Pages 6301-6306

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201401946

Keywords

honeycomb structure; layered oxides; Na3M2SbO6; Cathode; Na-ion batteries

Funding

  1. National Science Foundation of China [2133307, 21373155]

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A honeycomb layered Na3Ni2SbO6 is synthesized as a cathode for sodium-ion batteries. This new host material exhibits a high capacity of 117 mA h g(-1), a remarkable cyclability with 70% capacity retention over 500 cycles at a 2C rate, and a superior rate capability with >75% capacity delivered even at a very high rate of 30 C (6000 mA g(-1)). These results open a new perspective to develop high-capacity and high-rate Na-ion batteries for widespread electric-energy-storage applications.

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