Journal
ADVANCED MATERIALS
Volume 26, Issue 21, Pages 3561-3566Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201306258
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Funding
- Ministry of Science and Arts of the state of Baden-Wurttemberg
- STN
- BioInterfaces program of the Helmholtz association
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A novel adaptable network based on the reversible hetero Diels-Alder reaction of a cyanodithioester and cyclopentadiene is presented. Reversible between 50-120 degrees C, the adjustable and self-healing features of the network are evidenced via temperature dependent rheology experiments and repetitive tensile tests whereas the network's chemical structure is explored by temperature dependent H-1 MAS-NMR spectroscopy.
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