4.8 Article

Effective Solution- and Vacuum-Processed n-Doping by Dimers of Benzimidazoline Radicals

Journal

ADVANCED MATERIALS
Volume 26, Issue 25, Pages 4268-4272

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201400668

Keywords

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Funding

  1. National Defense Science and Engineering Graduate Research Fellowship
  2. National Science Foundation
  3. National Science Foundation (Materials Network Program) [DMR-1209468]
  4. National Science Foundation (MRSEC Program) [DMR-0820382, DMR-1305247]
  5. Air Force Office of Scientific Research [FA9550-12-1-01906]
  6. Division Of Materials Research
  7. Direct For Mathematical & Physical Scien [1305247] Funding Source: National Science Foundation
  8. Division Of Materials Research
  9. Direct For Mathematical & Physical Scien [1209468] Funding Source: National Science Foundation

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Benzimidazoline radical dimers that can be handled in air but that function as powerful reductants are reported and evaluated as n-dopants by solution- and vacuum processing. In several host materials, one of these dimers is found to have a more-consistent doping effect than a hydride-donor dopant analog. Notably, a record high room-temperature conductivity of 12.0 S cm(-1) is obtained for doped C-60.

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