Journal
ADVANCED MATERIALS
Volume 25, Issue 16, Pages 2284-2290Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201204738
Keywords
metal-organic frameworks; hybrid improper ferroelectrics; multiferroics; magnetoelectrics; jahn-teller; pseudo-rotation
Categories
Funding
- European Community [203523-BISMUTH]
- Italian Ministry of University Research through the FIRB project [RBAP117RWN]
- SPIN-CNR SEED project [PAQSE001]
- CINECA award under the ISCRA initiative
- U.S. Department of Energy through the LANL/LDRD Program
- [264098MAMA]
Ask authors/readers for more resources
On the basis of first-principles calculations, we design a novel Cr-based metal-organic framework to be both multiferroic and magnetoelectric. The compound shows a double-hybrid nature: it is a hybrid organic-inorganic compound and it shows hybrid improper ferroelectricity. Here, the coupling of non-polar distortions, such as Jahn-Teller pseudo-rotations and tilting, pave the way to a polar behavior, with the coupling being realized through hydrogen bonds.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available