4.8 Article

Addition of Dihydromethano Group to Fullerenes to Improve the Performance of Bulk Heterojunction Organic Solar Cells

Journal

ADVANCED MATERIALS
Volume 25, Issue 43, Pages 6266-6269

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201302607

Keywords

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Funding

  1. Funding Program for Next-Generation World-Leading Researchers [GR030]
  2. Strategic Promotion of Innovative Research and Development from the Japan Science and Technology Agency (JST)
  3. KAKENHI [22000008]
  4. Grants-in-Aid for Scientific Research [22000008] Funding Source: KAKEN

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Adding a compact dihydromethano (CH2) group to a 58 pi-indene fullerene (C-60(Ind)) creates a 56 pi-electron dihydromethano/indene fullerene (C-60(CH2)(Ind)) and raises the LUMO level with only a minimal increase in size. This class of compounds features reduced conjugation that raises the LUMO level, and a high electron mobility because of the small CH2 addend.

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