Journal
ADVANCED MATERIALS
Volume 25, Issue 14, Pages 2024-2028Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201203815
Keywords
photopolymerization; CuAAC; temporal control; high glass transition polymer; triazole linkage
Categories
Funding
- National Science Foundation [CHE 1214109]
- Industry/University Cooperative Research Center for Fundamentals and Applications of Photopolymerizations
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1214109] Funding Source: National Science Foundation
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The first bulk photopolymerization of multifunctional alkyne and azide monomers using the CuAAC reaction is successfully carried out from low molecular weight, nonviscous monomer resins. Compared to other traditional step-growth bulk photo polymerization, this approach readily provides crosslinked, high glass transition temperature polymers that incorporate triazole linkages throughout the polymer structure with great temporal control.
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