4.8 Article

Recent Advances in Organic One-Dimensional Composite Materials: Design, Construction, and Photonic Elements for Information Processing

Journal

ADVANCED MATERIALS
Volume 25, Issue 27, Pages 3627-3638

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201300325

Keywords

nanophotonics; organic nanomaterials; heterojunctions; information processing

Funding

  1. National Natural Science Foundation of China [21125315, 91022022, 51203165]
  2. Chinese Academy of Sciences
  3. Ministry of Science and Technology of China [2012YQ120060]
  4. Ministry of Science and Technology of China (National Basic Research 973 Program)

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Many recent activities in the use of one-dimensional nanostructures as photonic elements for optical information processing are explained by huge advantages that photonic circuits possess over traditional silicon-based electronic ones in bandwidth, heat dissipation, and resistance to electromagnetic wave interference. Organic materials are a promising candidate to support these optical-related applications, as they combine the properties of plastics with broad spectral tunability, high optical cross-section, easy fabrication, as well as low cost. Their outstanding compatibility allows organic composite structures which are made of two or more kinds of materials combined together, showing great superiority to single-component materials due to the introduced interactions among multiple constituents, such as energy transfer, electron transfer, exciton coupling, etc. The easy processability of organic 1D crystalline heterostructures enables a fine topological control of both composition and geometry, which offsets the intrinsic deficiencies of individual material. At the same time, the strong exciton-photon coupling and exciton-exciton interaction impart the excellent confinement of photons in organic microstructures, thus light can be manipulated according to our intention to realize specific functions. These collective properties indicate a potential utility of organic heterogeneous material for miniaturized photonic circuitry. Herein, focus is given on recent advances of 1D organic crystalline heterostructures, with special emphasis on the novel design, controllable construction, diverse performance, as well as wide applications in isolated photonic elements for integration. It is proposed that the highly coupled, hybrid optical networks would be an important material basis towards the creation of on-chip optical information processing.

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