4.8 Article

Two-Dimensional Supramolecular Electron Spin Arrays

Journal

ADVANCED MATERIALS
Volume 25, Issue 17, Pages 2404-2408

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201204274

Keywords

self-assembly; magnetic materials; supramolecular materials; stimuli-responsive materials; X-ray absorption spectroscopy

Funding

  1. National Centre of Competence in Research Nanosciences (NCCR-Nano)
  2. Swiss Nanoscience Institute (SNI)
  3. Swiss National Science Foundation [200020-137917, 206021-121461, 200020-132868, 200020-130266/1]
  4. Wolfermann Nageli Foundation
  5. Holcim Foundation for the Advancement of Scientific Research, Switzerland
  6. Swedish-Indian Research Links Programme, Sweden
  7. Swiss National Science Foundation (SNF) [206021_121461, 200020_132868, 200020_137917] Funding Source: Swiss National Science Foundation (SNF)

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A bottom-up approach is introduced to fabricate two-dimensional self-assembled layers of molecular spin-systems containing Mn and Fe ions arranged in a chessboard lattice. We demonstrate that the Mn and Fe spin states can be reversibly operated by their selective response to coordination/decoordination of volatile ligands like ammonia (NH3).

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