Journal
ADVANCED MATERIALS
Volume 24, Issue 42, Pages 5703-5707Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201202447
Keywords
gas adsorption; heterocycle; microporous polymer; selectivity
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Funding
- National Natural Science Foundation of China [50973037, 51173058]
- Program for New Century Excellent Talents in University from the Ministry of Education of China [NCET-10-0389]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1014]
- Hubei Province Natural Science Fund for Distinguished Young Scholars [2011CDA109]
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Aromatic heterocyclic microporous polymers with high surface areas are obtained by directly crosslinking of the heterocyclic monomers under mild conditions. Owing to the narrow pore system and the heteroatom-rich pore surface, these networks exhibit high CO2 adsorption capacity and selectivity. At 273 K, the CO2/N-2 selectivity of Py-1 is about 117, which is among the highest the reported microporous materials.
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