4.8 Article

High-Performance Membranes with Multi-permselectivity for CO2 Separation

Journal

ADVANCED MATERIALS
Volume 24, Issue 24, Pages 3196-3200

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201200638

Keywords

gas separation; membranes; crosslinking; poly(ethylene oxide); tertiary amino groups

Funding

  1. Natural Science Foundation of China [20836006]
  2. National Basic Research Program [2009CB623405]
  3. Science & Technology Pillar Program of Tianjin [10ZCKFSH01700]
  4. Program of Introducing Talents of Discipline to Universities [B06006]
  5. Ministry of Education [IRT0641]

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Multi-permselective membranes with diffusivity-selectivity, solubility-selectivity, and reactivity-selectivity for CO2 separation are prepared by interfacial polymerization. The membranes are able to efficiently separate CO2 from various light gases (H-2, CH4 and N-2) due to the optimized membrane structure and the comprehensive utilization of distinctions between CO2 and light gases in size, condensability, and reactivity.

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