Journal
ADVANCED MATERIALS
Volume 24, Issue 41, Pages 5625-5629Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201201846
Keywords
methylviologen; metal-organic frameworks; molecule-based magnets; luminescent properties; chemosensors
Categories
Funding
- MICINN (Spain) [CTQ2010-15364, MAT2010-16981, CSD2007-00010, CSD2006-00015, DPI2010-21103-C04-03]
- University of Valencia (Spain) [UV-INV-AE11-38904]
- Generalitat Valenciana (Spain) [PROMETEO/2009/108, GV/2012/051, ISIC/2012/002]
- ACIISI-Gobierno Autonomo de Canarias (Spain) [PIL-2070901]
- ESRF (France) [HS3902, 25-01-783]
- MFR
- CNRS (France)
- Generalitat Valenciana
- Dutch National Science Foundation (NWO-CW- VENI)
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On the road to chemical sensors: A novel 2D oxamato-based manganese(II)-copper(II) mixed-metal-organic framework (M'MOF) exhibiting non-linear fluorescence and long-range magnetic ordering is reported. This new luminescent nanoporous magnet features highly selective solvent-and gas sorption-induced optical switching behavior, opening the door to potential application for sensing of small molecules.
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