4.8 Article

Nitrogen-Enriched Core-Shell Structured Fe/Fe3C-C Nanorods as Advanced Electrocatalysts for Oxygen Reduction Reaction

Journal

ADVANCED MATERIALS
Volume 24, Issue 11, Pages 1399-1404

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201104392

Keywords

oxygen reduction reaction; electrocatalyst; iron carbide; nanorod; core shell

Funding

  1. National Science Foundation [CMMI-0900509, CBET-1033505]
  2. U.S. Department of Energy [DE-EE0003208]
  3. We Energies
  4. National Natural Science Foundation of China [20903055]
  5. Alexander von Humboldt Stiftung
  6. Div Of Civil, Mechanical, & Manufact Inn
  7. Directorate For Engineering [0900509] Funding Source: National Science Foundation

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A cost- effective route for the preparation of Fe3C- based core- shell structured catalysts for oxygen reduction reactions was developed. The novel catalysts generated a much higher power density (i. e., three times higher at Rex of 1 O) than the Pt/ C in microbial fuel cells. Furthermore, the N- Fe/ Fe3C@ C features an ultralow cost and excellent long- term stability suitable for mass production.

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