Journal
ADVANCED MATERIALS
Volume 24, Issue 48, Pages 6457-6461Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201202689
Keywords
conjugated polymers; polymer field-effect transistors; alkyl chain effect; branched alkyl chains
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Funding
- Ministry of Science and Technology [2009CB623601]
- National Natural Science Foundation of China
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Four polymers that contain alkyl chains branched at different positions on the polymer backbone are prepared. A polymer with 4-decyltetradecyl chains gives an impressive mobility of 3.62 cm(2) V-1 s(-1). This may arise from tighter polymer packing as well as stacking conformation change of the polymer backbone induced by the branching of the alkyl chains.
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