Journal
ADVANCED MATERIALS
Volume 25, Issue 4, Pages 618-622Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201202805
Keywords
lithium-ion batteries; lithium cobaltite; scanning transmission electron microscopy; twin boundaries; first-principles calculations
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Funding
- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [19053003] Funding Source: KAKEN
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Results of theoretical calculations are reported, examining the effect of a coherent twin boundary on the electrical properties of LiCoO2. This study suggests that internal interfaces in LiCoO2 strongly affect the battery voltage, battery capacity, and power density of this material, which is of particular concern if it is used in all-solid-state Li-ion batteries.
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