Journal
ADVANCED MATERIALS
Volume 24, Issue 6, Pages 839-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201104284
Keywords
conjugated polymers; structure-property relationships; self assembly; thin films; organic field-effect transistors
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Funding
- Freiburg Institute for Advanced Studies
- IRTG Soft Matter Science of the DFG
- DFG [SPP-1355]
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Macroscopic P3HT spherulitic crystals are grown in 25-nm-thick films via precise control of solvent swelling during polymer crystallization, which allow placement of transistor channels within single oriented crystal domains. Charge-transport anisotropy in the b-c (p-stacking & main chain) plane and the role of order-disorder grain boundaries are reported.
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