4.8 Article

Fluorescent Actuator Based on Microporous Conjugated Polymer with Intramolecular Stack Structure

Journal

ADVANCED MATERIALS
Volume 24, Issue 41, Pages 5604-5609

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201201967

Keywords

conjugated polymer; actuators; liquid crystal; fluorescence; sensor

Funding

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF)
  2. Korea government (MEST) [2012-0000633, 20120001714, 2012-0005143]
  3. R&D Program (nanotechnology convergence project for commercialization and platform) [10036099]
  4. Ministry of Knowledge Economy (MKE), Republic of Korea

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Fluorescent bilayer film, consisting of an active layer of a microporous conjugated polymer with intramolecular stack structure, is successfully fabricated. This bilayer film shows the simultaneous occurrence in actuation and fluorescence change in response to external chemical stimuli. Highly reversible uncurling-curling movement, accompanied with changes in fluorescence color and intensity, is achieved upon sequential exposure to alcohol and water.

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