4.8 Article

Vapor Diffusion Sol-Gel Synthesis of Fluorescent Perovskite Oxide Nanocrystals

Journal

ADVANCED MATERIALS
Volume 24, Issue 11, Pages 1434-1438

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201104645

Keywords

perovskites; BaZrO3; phosphors; europium; nanoparticles

Funding

  1. Department of Energy Office of Basic Energy Sciences [DE-FG02-11ER46826]
  2. Department of Chemistry
  3. Dornsife College of Letters, Arts, and Science at University of Southern California
  4. Research Corporation for Science Advancement

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A model system consisting of Eu3+ as the activator ion and BaZrO3 as the host lattice is employed to demonstrate the potential of the vapor diffusion sol- gel method as a hydrolytic approach to the synthesis of fluorescent alkalineearth perovskite oxide nanocrystals under ultrabenign conditions. The resulting nanocrystals are suitable precursors for nanostructured red- emitting phosphors.

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