Journal
ADVANCED MATERIALS
Volume 23, Issue 32, Pages 3723-+Publisher
WILEY-BLACKWELL
DOI: 10.1002/adma.201101759
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Funding
- U.S. Department of Energy (DOE) [DE-SC0001015, DE-FC36-07GO17033, DE-AR0000073]
- National Science Foundation (NSF) [CBET-0930079, CHE-0911207]
- Welch Foundation [A-1725]
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Highly stable porous polymer networks (PPNs) are synthesized through a Yamamoto homocoupling reaction between tetrahedral monomers. Among those polymers, PPN-4 shows exceptionally high Langmuir surface area of 10063 m(2) g(-1) (SA(BET): 6461 m(2) g(-1)). It also exhibits ultra high hydrogen, methane, and carbon dioxide storage capacities. These properties make it a perfect adsorbent for clean energy applications.
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