4.8 Article

Rational Design and Engineering of Quantum-Dot-Sensitized TiO2 Nanotube Arrays for Artificial Photosynthesis

Journal

ADVANCED MATERIALS
Volume 23, Issue 16, Pages 1883-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201004576

Keywords

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Funding

  1. National Research Foundation (NRF) via National Research Laboratory [R0A-2008-000-20041-0]
  2. Engineering Research Center [2008-0062205]
  3. Converging Research Center [2009-0082276]
  4. KAIST Energy Environment Water Sustainability (EEWS) Initiative
  5. Ministry of Education, Science & Technology (MoST), Republic of Korea [N01110018] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  6. National Research Foundation of Korea [2010-50207] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Chiral compounds are successfully photosynthesized by coupling redox biocatalysis with the photoregeneration of nicotinamide cofactors on quantum-dot-sensitized TiO2 nanotubes under visible light irradiation. Nanotubular morphology and hybridization of TiO2 with CdS enables highly efficient photoregeneration of cofactors by ensuring better diffusion of reaction species and rapid charge separation.

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