4.8 Article

Largely Enhanced Efficiency with a PFN/Al Bilayer Cathode in High Efficiency Bulk Heterojunction Photovoltaic Cells with a Low Bandgap Polycarbazole Donor

Journal

ADVANCED MATERIALS
Volume 23, Issue 27, Pages 3086-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201101319

Keywords

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Funding

  1. National Natural Science Foundation of China [50773023, 50990065, 51010003, 60906032]
  2. National Basic Research Program of China [2009CB623600]
  3. SCUT [2009ZZ0003]

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Quinoxaline-containing poly(4,5-ethylene-2,7-carbazole) (PECz-DTQx) shows a high efficiency of 6.07% in solar cells with a PFN/Al bilayer cathode. This is higher than the efficiency achieved with sole Al (3.99%) or with Ca/Al (4.52%) cathodes. A bilayer cathode could be valuable in device configurations to achieve high efficiency in combination with a high-performance polymer donor.

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