4.8 Article

Organic Field-Effect Transistors based on Highly Ordered Single Polymer Fibers

Journal

ADVANCED MATERIALS
Volume 24, Issue 3, Pages 417-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201103057

Keywords

conjugated donor-acceptor copolymer; single polymer fibers; organic electronics; field-effect transistors; self-assembly

Funding

  1. German Science Foundation (Korean-German IR TG)
  2. European Community [212311]
  3. DFG [SPP 1355, MU 334/32-1, SPP 1459]
  4. ESF [09-EuroGRAPHENE-FP-001]

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Ultrahigh-mobility organic field-effect transistors (OFETs) based on a CDT-BTZ donor-acceptor copolymer are realized by reaching high molecular order and pronounced alignment in single fibers within a short OFET channel via solution processing. The macromolecules directionally self-assemble in a quasi crystal-like order in the fibers providing in this way an unhindered charge carrier pathway with mobilities as high as 5.5 cm(2) V-1 s(-1).

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