4.8 Article

Metal-containing Polymers via Electropolymerization

Journal

ADVANCED MATERIALS
Volume 24, Issue 3, Pages 332-345

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201103420

Keywords

electrochemistry; electropolymerization; inorganic-organic hybrid materials; metallopolymers; metal-containing polymers

Funding

  1. Fonds der Chemischen Industrie
  2. Dutch Polymer Institute (DPI, technology area HTE)
  3. German Federal Ministry of Education and Research (Excellence Research and Innovation in East Germany: PhoNa)
  4. Thuringer Ministerium fur Bildung, Wissenschaft und Kultur [B 514-09049: PhotoMic]

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Electropolymerization represents a suitable and well-established approach for the assembly of polymer structures, in particular with regard to the formation of thin, insoluble films. Utilization of monomers that are functionalized with metal complex units allows the combination of structural and functional benefits of polymers and metal moieties. Since a broad range of both electropolymerizable monomers and metal complexes are available, various structures and, thus, applications are possible. Recent developments in the field of synthesis and potential applications of metal-functionalized polymers obtained via electropolymerization are presented, highlighting the significant advances in this field of research.

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