4.8 Article

Evidence for a New Two-Dimensional C4H-Type Polymer Based on Hydrogenated Graphene

Journal

ADVANCED MATERIALS
Volume 23, Issue 39, Pages 4497-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201102019

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Funding

  1. EU
  2. DFG [VY 64/1-1, GR 3708/1-1]
  3. Austrian Academy of Sciences
  4. Japan Science and Technology Agency (JST)
  5. RFBR
  6. SPbSU

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A new polymer with C4H stoichiometry based on graphene is synthesized in situ using template-induced polymerization of self-organizing hydrogen adsorbates on graphene. The polymerization is observed live on the surface of graphene by photoemission spectroscopy. Photoemission spectroscopy allows accurate determination of the carbon/hydrogen stoichiometry, an aspect that is extremely important for understanding functionalized graphene.

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