4.8 Article

Radical Polymer-Wrapped SWNTs at a Molecular Level: High-Rate Redox Mediation Through a Percolation Network for a Transparent Charge-Storage Material

Journal

ADVANCED MATERIALS
Volume 23, Issue 38, Pages 4440-+

Publisher

WILEY-BLACKWELL
DOI: 10.1002/adma.201102372

Keywords

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Funding

  1. World-Class University (WCU) at GIST through MEST, Korea [R31-2008-000-10026- 0]
  2. MEXT, Japan [19105003, 21655043, 21550120, 21106519]
  3. Global COE at Waseda University
  4. Grants-in-Aid for Scientific Research [19105003, 21106519, 21655043, 21550120] Funding Source: KAKEN

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A transparent nanocomposite of a radical polymer, the poly(2,2,6,6-tetramethylpiperidine-1-oxy-4-yl methacrylate) (PTMA), and single-walled carbon nanotubes (SWNTs) display a reversible charging and discharging, allowing full discharge in seconds. This is ascribed to the reversible electrochemical reaction of the pendant radical group in PTMA aided by both PTMA wrapping at a molecular level and the SWNT network for electrical conduction.

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