Journal
ADVANCED MATERIALS
Volume 22, Issue 3, Pages 415-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200901846
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Funding
- MEST INRF [2009-0082083]
- National Research Foundation of Korea [2009-0082083, 2010-50181] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Simple physical blending of SiO2 and ethylcapped Ge gels leads to flexible dimensional control of Ge nanoparticles, and an increasing weight fraction of the latter leads to ordered 3D porous nanoparticle assemblies (see figure). The long-range ordering of the 3D porous Ge nanoparticles and their very thin pore wall thicknesses (<20 nm) induce excellent cycling performance, showing only a 2% capacity decrease after 100 cycles.
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