4.8 Article

Lithium Iron Borates as High-Capacity Battery Electrodes

Journal

ADVANCED MATERIALS
Volume 22, Issue 32, Pages 3583-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201001039

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan [19205027]
  2. New Energy and Industrial Technology Development Organization (NEDO)
  3. Grants-in-Aid for Scientific Research [19205027] Funding Source: KAKEN

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Beyond the limited lithium storage capability of the (PO4)(3-)-based compound, LiFePO4 (170 mAh/g), which is currently recognized as the most promising lithium battery cathode for large-scale application, a compound with the lightest small triangle oxyanion unit (BO3)(3-), namely LiFeBO3, exhibits a much larger reversible capacity of ca. 200 mAh/g with surprisingly small volume change of ca. 2%.

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