Journal
ADVANCED MATERIALS
Volume 22, Issue 3, Pages 367-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200900529
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Replacing a carbon atom with silicon (see figure) on the main chain of a conjugated polythiophene gives a polysilole with higher crystallinity, improved charge transport, reduced bimolecular recombination, and reduced formation of charge-transfer complexes when blended with a fullerene derivative. Optimized bulk heterojunction solar cells using this blend give certified efficiencies of 5.2% under AM 1.5 illumination.
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