4.8 Article

Ordered Nanosphere Alignment of Porphyrin for the Improvement of Nonlinear Optical Properties

Journal

ADVANCED MATERIALS
Volume 22, Issue 32, Pages 3532-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200904421

Keywords

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Funding

  1. National Nature Science Foundation of China [20531060, 20831160507, 10874187, 20873155, 20721061]
  2. National Basic Research 973 Program of China

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Using the small molecule TEOP (5,10,15,20-[1,4-benzodioxane-6-carboxalde]porphyrin), the in situ assembly is a very convenient and efficient approach for fabricating high-quality ordered patterns. The well-ordered patterns possess strong saturated absorptive and self-defocusing nonlinearities while the TEOP solution exhibit reverse saturated absorption. The value of the nonlinear absorption coefficient of the TEOP ordered pattern and solution differed by three orders of magnitude. [GRAPHICS]

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