Journal
ADVANCED MATERIALS
Volume 22, Issue 29, Pages 3185-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200904317
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- MEXT of Japan [19049008]
- Grants-in-Aid for Scientific Research [19049008] Funding Source: KAKEN
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Glutathione-protected Au-25 as well as Au-n (n = 15, 18, 22, 29, 33, 39) clusters adsorbed on TiO2 electrodes exhibit anodic photocurrents and negative shifts of photopotential in response to visible and/or near-infrared light. (400 < lambda < 900 nm) on the basis of HOMO-LUMO and similar transitions, indicating that the electrodes are applicable to the conversion of light to electricity (see figure).
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