4.8 Article

Thermally Induced Reversible Phase Transformations Accompanied by Emission Switching Between Different Colors of Two Aromatic-Amine Compounds

Journal

ADVANCED MATERIALS
Volume 21, Issue 31, Pages 3165-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200803432

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Funding

  1. National Natural Science Foundation of China [50733002]
  2. Major State Basic Research Development Program [2009CB623600]
  3. Program for Changjiang Scholars and Innovative Research Teams in a University [IRT0422]
  4. 111 Project [1306009]

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Thermally driven reversible emission switching between different colors and solid-phase transformation are investigated for two aromatic-amine compounds bearing trifluoromethyl (CF3) groups. The phase-dependent emission properties are attributed to the different molecular packing properties and changeable molecular geometry for different solid phases (see figure).

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