4.8 Article

Facile Synthesis and Shape Evolution of Single-Crystal Cuprous Oxide

Journal

ADVANCED MATERIALS
Volume 21, Issue 20, Pages 2068-2071

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200802783

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Funding

  1. National Key Project of Fundamental Research [2005CB6236-05]
  2. Shanghai Nanotechnology Promotion Center [0852nm01900]

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Various morphologies of single-crystal Cu2O such as cube, octahedron, {110} truncated octahedron, and microrhombic dodecahedron with {110} surfaces are prepared in high yield through a facile solution-based one-step reduction method in an alkaline H2O/ethanol/oleic acid system in the presence of d-(+)-glucose. The formation mechanism of these microcrystals has been clarified as the synergic effect of oriented attachment and ripening mechanism.

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