4.8 Article

Polaron Localization at Interfaces in High-Mobility Microcrystalline Conjugated Polymers

Journal

ADVANCED MATERIALS
Volume 21, Issue 37, Pages 3759-3763

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200900326

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Funding

  1. Engineering and Physical Sciences Research Council
  2. Royal Society for a Dorothy Hodgkin postgraduate award
  3. Korea Evaluation Institute of Industrial Technology (KEIT) [KI001909] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The charge-induced optical absorptions of two-dimensional polarons in semicrystalline, high-mobility conjugated polymers are investigated as a function of distance from an interface with polymer gate dielectrics of different dielectric constants. For high-k dielectrics, polarons in the accumulation layer at the interface are found to be more localized than those in the bulk.

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