Journal
ADVANCED MATERIALS
Volume 21, Issue 1, Pages 102-106Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200801602
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Funding
- U.S. Department of Energy by Lawrence Livermore National Laboratory [W-7405-Eng-48, DE-AC52-07NA27344]
- Laboratory Directed Research and Development Program at LLNL [07-LW-056]
- Department of Energy, Office of Biological and Environmental Research
- National Institutes of Health, National Center for Research Resources, Biomedical Technology Program
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The detailed interactions between hydrated bromine ions and a number of graphene-like surfaces are elucidated for the first time. A common edge site that exhibits preferential binding of bromide is observed for all materials. The local structure around the hydrated bromide in this interaction region is that of the ion binding to a zigzag, convex site on the graphene sheet edge, consistent with predictions of a recent theoretical model.
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