Journal
ADVANCED MATERIALS
Volume 22, Issue 9, Pages 986-+Publisher
WILEY-BLACKWELL
DOI: 10.1002/adma.200903217
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Funding
- DOE [DE-FG02-02ER45999]
- NSF [CHE-0610019, NSF-9974899, NSF-9807975]
- Welch Foundation [A-1449]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0957840] Funding Source: National Science Foundation
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Single crystals of a new structure type for the M+(TCNQ)(center dot-) binary family are isolated from reactions of dihalogenated TCNQ derivatives and Cu-I ions (see figure; Cu: pink C: black, N: blue, Br: orange, H: light blue). The new compound Cu(TCNQCl(2)) exhibits the highest conductivity of the M+(TCNQ)(center dot-) series to date, despite the larger separation of TCNQCl(2) units in the stacks. Conductive properties of Cu(TCNQX(2)) where X=Cl, Br is attributed to charge-carrier transport through copper ions, which is unprecedented in M+(TCNQ)(center dot-) materials.
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