Journal
ADVANCED MATERIALS
Volume 20, Issue 1, Pages 37-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200701221
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The self assembly of peptide hydrogelators that carry aromatic substituents can be modeled by a novel nanocylindrical architecture. The proposed model suggests that the nanocylinders are formed by anti-parallel beta-sheets interlocked by the pi-stacking interactions of fluorenyl groups and phenyl rings. This explanation is consistent with the structures observed in TEM and the data obtained by a variety of spectroscopic techniques.
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