4.8 Article

Stabilized Nanoporous Metals by Dealloying Ternary Alloy Precursors

Journal

ADVANCED MATERIALS
Volume 20, Issue 24, Pages 4883-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200702760

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Funding

  1. US Department of Energy, Office of Basic Energy Sciences [IDE-FG02-05ER15727]

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A small percentage of platinum added to silver/gold alloys that are then electrochemically dealloyed yields an extremely high surface area nanoporous metal, with pore size less than 4 mn, as shown in the figure (scale bar = 5 nm). The presence of surface platinum stabdizes the nanostructure to coarsening in air and electrolyte.

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