Journal
ADVANCED MATERIALS
Volume 20, Issue 2, Pages 246-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200701766
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Mesoporous silica films with cylindrical pores oriented normal to the substrate are prepared by selective deposition of silica within the poly(hydroxy styrene) domains of poly(alpha-methyl styrene-b-hydroxy styrene) template films using supercritical carbon dioxide as a delivery medium. Atomic force microscopy, electron microscopy, and grazing incidence small angle X-ray scattering (see figure) studies confirm the vertical alignment of the cylindrical pores.
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