4.8 Article

Hierarchical Self-Assembly of Edge-On Nanocolumnar Superstructures of Large Disc-Like Molecules

Journal

ADVANCED MATERIALS
Volume 20, Issue 20, Pages 3854-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200801428

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Funding

  1. Centre National de la Recherche Scientifique (CNRS)
  2. Commissariat l'Energie Atomique (CEA)
  3. EU project NAIMO [NMP4-CT-2004-500355]
  4. German Science Foundation

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Long uniaxial edge-on nanocolumnar stacks of dodecyl-substituted hexa-peri-hexabenzocoronene grow spontaneously at the liquid/solid interface as a result of a hierarchical self-assembly process. Supramolecular multilayered architectures as complex as {HOPG/face-on/edge-on/edge-on} and {HOPG/face-on/edge-on/face-on} are produced, paving the way towards future applications in organic nanodevices. [GRAPHICS]

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