4.8 Article

A Phosphorescent Ir(III) Complex for Selective Fluoride Ion Sensing with a High Signal-to-Noise Ratio

Journal

ADVANCED MATERIALS
Volume 20, Issue 20, Pages 3820-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200702667

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Funding

  1. Korea Science and Engineering Foundation (KOSEF) through the National Research Lab. Program, Ministry of Education, Science and Technology [2006-03246]
  2. National Research Foundation of Korea [2004-02466] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A highly phosphorescent Ir(III) complex, containing a dimesitylboryl group in its coordinative phenylpyridine ligand, exhibited a phosphorescence colorimetric and ratiometric fluoride ion-selective sensing behavior and enabled facile signal purification through time-gated acquisition. Poly(methylmethacrylate) films doped with the Ir(III) complex were used to successfully detect fluoride ion in aqueous media.

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