4.8 Article

Electronic Current Transport through Molecular Monolayers: Comparison between Hg/Alkoxy and Alkyl Monolayer/Si(100) Junctions

Journal

ADVANCED MATERIALS
Volume 20, Issue 20, Pages 3931-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200800659

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Funding

  1. French Embassy in Israel
  2. Israel Science Foundation, Jerusalem
  3. Schmidt Minerva Centre
  4. Minerva Foundation (Munich)
  5. US-Israel Binational Science Foundation
  6. National Science Foundation [DMR-0705920, DMR-0213706]

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Electronic current transport through alkoxy and alkyl monolayer-based junctions is presented. Monolayers are prepared on n-Si(100) with sufficiently high quality to reliably investigate the actual molecular effect of each monolayer on their current-voltage characteristics. The results show that extending the Si-binding chemistry from alkene to alcohol is feasible which should significantly facilitate preparation of monolayers with modified molecules.

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