Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 24, Issue 34, Pages 5435-5442Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201401002
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Funding
- Center for Electrical Energy Storage: Tailored Interfaces, an Energy Frontier Research Center - US Department of Energy, Office of Science, Office of Basic Energy Sciences
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886]
- NSERC Postdoctoral Fellowship, Canada
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Metal sulfides are an important class of functional materials possessing exceptional electrochemical performance and thus hold great promise for rechargeable secondary batteries. In this work, we deposited gallium sulfide (GaSx, x = 1.2) thin films by atomic layer deposition (ALD) onto single-walled carbon nanotube (SWCNT) powders. The ALD GaSx was performed at 150 degrees C, and produced uniform and conformal amorphous films. The resulting core-shell, nanostructured SWCNT-GaSx composite exhibited excellent electrochemical performance as an anode material for lithium-ion batteries (LIBs), yielding a stable capacity of approximate to 575 mA g(-1) at a current density of 120 mA g(-1) in the voltage window of 0.01-2 V, and an exceptional columbic efficiency of >99.7%. The GaSx component of the composite produced a specific capacity of 766 mA g(-1), a value two times that of conventional graphite anodes. We attribute the excellent electrochemical performance of the composite to four synergistic effects: 1) the uniform and conformal ALD GaSx coating offers short electronic and Li-ion pathways during cycling; 2) the amorphous structure of the ALD GaSx accommodates stress during lithiation-delithiation processes; 3) the mechanically robust SWCNT framework also accommodates stress from cycling; 4) the SWCNT matrix provides a continuous, high conductivity network.
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