Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 25, Issue 3, Pages 481-489Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201402833
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Funding
- National Basic Research Program of China [2013CB934001]
- National Natural Science Foundation of China [51101139]
- Fundamental Research Funds for the Central Universities [2014XZZX002-03]
- Key Science and Technology Innovation Team of Zhejiang Province [2010R50013]
- Program for Innovative Research Team in University of Ministry of Education of China [IRT13037]
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Na-ion Batteries have been considered as promising alternatives to Li-ion batteries due to the natural abundance of sodium resources. Searching for high-performance anode materials currently becomes a hot topic and also a great challenge for developing Na-ion batteries. In this work, a novel hybrid anode is synthesized consisting of ultrafine, few-layered SnS2 anchored on few-layered reduced graphene oxide (rGO) by a facile solvothermal route. The SnS2/rGO hybrid exhibits a high capacity, ultralong cycle life, and superior rate capability. The hybrid can deliver a high charge capacity of 649 mAh g(-1) at 100 mA g(-1). At 800 mA g(-1) (1.8 C), it can yield an initial charge capacity of 469 mAh g(-1), which can be maintained at 89% and 61%, respectively, after 400 and 1000 cycles. The hybrid can also sustain a current density up to 12.8 A g(-1) (approximate to 28 C) where the charge process can be completed in only 1.3 min while still delivering a charge capacity of 337 mAh g(-1). The fast and stable Na-storage ability of SnS2/rGO makes it a promising anode for Na-ion batteries.
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