Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 24, Issue 20, Pages 2930-2937Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201303902
Keywords
graphene aerogels; iron nitride; iron phthalocyanine; oxygen reduction reaction; synergistic effects
Categories
Funding
- NSFC [51125001, 51172005, 90922033]
- National Basic Research Program of China [2010CB934601]
- Doctoral Program [20120001110078]
- New Century Talent of the Education Ministry of China [NCET-09-0177]
- Natural Science Foundation of Beijing [2122022]
- Aeronautic Science Fund [2010ZF71003]
- Yok Ying Tung Fund [122043]
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It is extremely desirable but challenging to create highly active, stable, and low-cost catalysts towards oxygen reduction reaction to replace Pt-based catalysts in order to perform the commercialization of fuel cells. Here, a novel iron nitride/nitrogen doped-graphene aerogel hybrid, synthesized by a facile two-step hydrothermal process, in which iron phthalocyanine is uniformly dispersed and anchored on graphene surface with the assist of - stacking and oxygen-containing functional groups, is reported. As a result, there exist strong interactions between Fe x N nanoparticles and graphene substrates, leading to a synergistic effect towards oxygen reduction reaction. It is worth noting that the onset potential and current density of the hybrid are significantly better and the charge transfer resistance is much lower than that of pure nitrogen-doped graphene aerogel, free Fe x N and their physical mixtures. The hybrid also exhibits comparable catalytic activity as commercial Pt/C at the same catalyst loading, while its stability and resistance to methanol crossover are superior. Interestingly, it is found that, apart from the active nature of the hybrid, the large surface area and porosity are responsible for its excellent onset potential and the high density of Fe-N-C sties and small size of Fe x N particles boost charge transfer rate.
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