Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 23, Issue 29, Pages 3701-3709Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201203711
Keywords
cathodoluminescence; nanostructures; ZnS
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Funding
- National Natural Science Foundation of China [91123006, 21001028, 51002032]
- National Basic Research Program of China [2012CB932303]
- Shanghai Chenguang Foundation [11CG06]
- Shanghai Pujiang Program [11PJ1400300, 12PJ1400300]
- Shanghai Shu Guang Project, Science and Technology Commission of Shanghai Municipality [11520706200]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
- Programs for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning and for New Century Excellent Talents in University [NCET-11-0102]
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Spatially and spectrally resolved cathodoluminescence (CL) is one of the most effective methods to explore the optical properties of a nanomaterials and reveals the spatial distribution as well as the correlation between the luminescence and the sample morphology and microstructure. Here, CL modulation of ZnS nanostructures by controlled morphologies, Fe/Mn doping, and measurement temperature is demonstrated. High quality ZnS nanobelts and nanorods are synthesized on an Au-coated Si substrate and an Au-coated GaAs substrate via a facile thermal evaporation route. A room-temperature sharp ultraviolet (UV) lasing-like peak in various ZnS is achieved. The main UV luminescence peaks appear at wavelengths between 330 and 338 nm. The low temperature (32 K) CL spectrum consists of a narrow and strong UV peak centered at 330 nm and two broad, low-intensity peaks in the visible region (514 and 610 nm). Temperature-dependent CL from such single-crystalline ZnS nanobelts in the temperature range of 32 to 296 K reveals two UV peaks at 3.757 and 3.646 eV. The effects of Fe doping and Fe/Mn co-doping on the CL property of ZnS nanobelts are further investigated. These results imply that ZnS nanostructures can be used for potential luminescent materials as well as short-wavelength nanolaser light sources.
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