Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 23, Issue 32, Pages 4011-4019Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201203602
Keywords
grafting; photoligation chemistry; surface patterning; azobenzene; photoresponse
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Funding
- MINECO, Spain [MAT2011-27978-C02-01]
- Fondo Europeo de Desarrollo Regional (FEDER)
- Gobierno de Aragon
- CSIC
- Karlsruhe Institute of Technology (KIT)
- German Research Council (DFG)
- ministry of science and arts of the state of Baden-Wurttemberg
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The preparation of patterned photoswitchable surfaces by employing the nitrile imine-mediated tetrazole ene cycloaddition (NITEC) photoinduced reaction in the presence of dipolarophiles based on photoresponsive azobenzene moieties is reported. The dipolarophile used is a maleimide carrying either an azobenzene unit or a first generation dendron containing two azobenzene units. X-ray photoelectron spectroscopy (XPS) is employed to analyze the functionalized silicon wafers, while time-of-flight secondary ion mass spectrometry (ToF-SIMS) evidences the spatial control of the functionalization of the surface achieved by using a micropatterned shadow mask. Water contact angle measurements and optical inspection observing the behavior of a water droplet demonstrate the photoinduced change on wettability of the structured functionalized surfaces due to the reversible trans-to-cis isomerization of the azobenzene moities.
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