4.8 Article

Microorganism-Derived Heteroatom-Doped Carbon Materials for Oxygen Reduction and Supercapacitors

Journal

ADVANCED FUNCTIONAL MATERIALS
Volume 23, Issue 10, Pages 1305-1312

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201201643

Keywords

carbon materials; biomass; electrochemistry; oxygen reduction; supercapacitors

Funding

  1. National Natural Science Foundation of China [20890022]
  2. National Key Basic Research Development Project of China [2010CB933602]

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Heteroatom-doped carbon (HDC) has attracted tremendous attention due to its promising application in energy conversion and storage. Herein, due to its abundance high rate of reproduction, the microorganism, Bacillus subtilis, is selected as a precursor. An effective ionothermal process is adopted to produce the HDCs. Using acid activation, the obtained sample exhibits excellent electrocatalytic activity, long-term stability, and excellent resistance to crossover effects in oxygen reduction. Additionally, the base-treated sample exhibits superior performance in capacitors to most commercially available carbon materials. Even at a high current density, a relatively high capacitance is retained, indicating a great potential for direct application in energy storage.

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